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Bavarder sur Internet· A convenient synthetic strategy is reported for the series of complexes Ir(pp)3 3 (where pp = phen Me2phen and Me4phen) through the intermediacy of the appropriate Ir(pp)2(CF3SO3)2 species. In the case of Ir(phen)3 3 the cation was resolved into its enantiomeric forms for which the absolute configurations were determined by X-ray diffraction. The availability for the first time of
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Bavarder sur Internet· Bis(2 2′-bipyridyl)ruthenium(ii) complexes of four chelating ligands that contain benzoxazole or benzothiazole rings have been prepared and characterized by NMR spectroscopy visible absorption spectroscopy electrochemical measurements and in two cases by X-ray crystallography. The incorporation of these ring systems has a marked effect on the electronic properties of the resulting
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Bavarder sur Internet· Atmospheric acidity is increasingly determined by carbon dioxide and organic acids1–3. Among the latter formic acid facilitates the nucleation of cloud droplets4 and contributes to the acidity
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Bavarder sur Internet· Tidal seawater inundation of coastal acid sulfate soils can generate Fe- and SO4-reducing conditions in previously oxic-acidic sediments. This creates potential for mobilization of As during the redox transition. We explore the consequences for As by investigating the hydrology porewater geochemistry solid-phase speciation and mineralogical partitioning of As across two tidal fringe
Bavarder sur Internet· A convenient synthetic strategy is reported for the series of complexes Ir(pp)3 3 (where pp = phen Me2phen and Me4phen) through the intermediacy of the appropriate Ir(pp)2(CF3SO3)2 species. In the case of Ir(phen)3 3 the cation was resolved into its enantiomeric forms for which the absolute configurations were determined by X-ray diffraction. The availability for the first time of
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